Distribution of polychlorinated naphthalene congeners in environmental and source-related samples

被引：87

作者：

Jarnberg, U ^{[1
]}

Asplund, L ^{[1
]}

deWit, C ^{[1
]}

Egeback, AL ^{[1
]}

Wideqvist, U ^{[1
]}

Jakobsson, E ^{[1
]}

机构：

[1] UNIV STOCKHOLM,WALLENBERG LAB,DEPT ENVIRONM CHEM,S-10691 STOCKHOLM,SWEDEN

来源：

ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY | 1997年 / 32卷 / 03期

关键词：

D O I：

10.1007/s002449900181

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Polychlorinated naphthalene (CN) congener profiles in environmental and source related samples were compared graphically and by principal component analysis. Samples investigated included biological, sediment, water, and air samples, technical polychlorinated biphenyl (PCB) and polychlorinated naphthalene (PCN) formulations, as well as municipal waste incineration (MWI) fly ash and graphite electrode sludge. Biological samples showed a preferential enrichment of planar, 1,3,5,7-substituted tetra-, penta-, and hexachlorinated congeners and most of these samples showed profiles that displayed some similarity to those found in the technical PCB formulations. Sediment samples representing diffuse pollution, i.e., sediment samples from remote sites, showed an elevated abundance of the planar hexa- and heptaCN congeners (1,2,3,4,6,7-/1,2,3,5,6,7- and 1,2,3,4,5,6,7-). The CN congener profile found in these sediment samples and the two air samples were more similar to the technical PCB formulations than to the investigated MWI and graphite sludge samples. Samples from three PCB contaminated lakes displayed similar congener profiles as Aroclor 1242, 1254 and Clophen A40. Two sediment samples and a pike sample collected from the vicinity of a chloroalkali plant showed profiles that were closely related to the investigated graphite electrode sludge sample. None of the environmental samples displayed profiles similar to low or medium chlorinated technical PCN (Halowax 1099, 1013, and 1014).

引用

页码：232 / 245

页数：14

共 40 条

[11] DETERMINATION OF POLYCHLORINATED NAPHTHALENES IN POLYCHLORINATED BIPHENYL PRODUCTS VIA CAPILLARY GAS-CHROMATOGRAPHY MASS-SPECTROMETRY AFTER SEPARATION BY GEL-PERMEATION CHROMATOGRAPHY [J].

HAGLUND, P ;

JAKOBSSON, E ;

ASPLUND, L ;

ATHANASIADOU, M ;

BERGMAN, A .

JOURNAL OF CHROMATOGRAPHY, 1993, 634 (01) :79-86

[12] ISOLATION OF MONO-ORTHO AND NON-ORTHO POLYCHLORINATED-BIPHENYLS FROM BIOLOGICAL SAMPLES BY ELECTRON-DONOR ACCEPTOR HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY USING A 2-(1-PYRENYL)ETHYLDIMETHYLSILYLATED SILICA COLUMN [J].

HAGLUND, P ;

ASPLUND, L ;

JARNBERG, U ;

JANSSON, B .

CHEMOSPHERE, 1990, 20 (7-9) :887-894

[13] SWEDISH DIOXIN SURVEY - DETERMINATION OF 2,3,7,8-TCDD TOXIC EQUIVALENT FACTORS FOR SOME POLYCHLORINATED-BIPHENYLS AND NAPHTHALENES USING BIOLOGICAL TESTS [J].

HANBERG, A ;

WAERN, F ;

ASPLUND, L ;

HAGLUND, E ;

SAFE, S .

CHEMOSPHERE, 1990, 20 (7-9) :1161-1164

[14]

Imagawa T., 1993, Journal of Environmental Chemistry, V3, P221

[15] SYNTHESIS AND CRYSTALLOGRAPHY OF 2 HEXACHLORO-NAPHTHALENES .2. 1,2,4,5,6,8-HEXACHLORO-NAPHTHALENE AND 1,2,4,5,7,8-HEXACHLORONAPHTHALENE [J].

JAKOBSSON, E ;

LONNBERG, C ;

ERIKSSON, L .

ACTA CHEMICA SCANDINAVICA, 1994, 48 (11) :891-898

[16] SYNTHESIS AND CRYSTALLOGRAPHY OF 1,2,3,4,6,7-HEXACHLORONAPHTHALENE AND 1,2,3,5,6,7-HEXACHLORONAPHTHALENE [J].

JAKOBSSON, E ;

ERIKSSON, L ;

BERGMAN, A .

ACTA CHEMICA SCANDINAVICA, 1992, 46 (06) :527-532

[17] MULTIRESIDUE METHOD FOR THE GAS-CHROMATOGRAPHIC ANALYSIS OF SOME POLYCHLORINATED AND POLYBROMINATED POLLUTANTS IN BIOLOGICAL SAMPLES [J].

JANSSON, B ;

ANDERSSON, R ;

ASPLUND, L ;

BERGMAN, A ;

LITZEN, K ;

NYLUND, K ;

REUTERGARDH, L ;

SELLSTROM, U ;

UVEMO, UB ;

WAHLBERG, C ;

WIDEQVIST, U .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1991, 340 (07) :439-445

[18]

JARNBERG U, 1993, ENVIRON SCI TECHNOL, V27, P1364

[19] RESIDUE ANALYSIS OF SEDIMENT AND SEWAGE SLUDGE FOR ORGANOCHLORINES IN PRESENCE OF ELEMENTAL SULFUR [J].

JENSEN, S ;

RENBERG, L ;

REUTERGARDH, L .

ANALYTICAL CHEMISTRY, 1977, 49 (02) :316-318

[20] WET AND DRY DEPOSITION OF CHLORINATED DIOXINS AND FURANS [J].

KOESTER, CJ ;

HITES, RA .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1992, 26 (07) :1375-1382

← 1 2 3 4 →