Recent advances in porphyrinic metal-organic frameworks: materials design, synthetic strategies, and emerging applications

被引:123
作者
Burnett, Brandon J. [1 ]
Barron, Paul M. [1 ]
Choe, Wonyoung [1 ]
机构
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
来源
CRYSTENGCOMM | 2012年 / 14卷 / 11期
关键词
SINGLE-CRYSTAL TRANSFORMATIONS; COORDINATION POLYMERS; COMPLEXES; RESTRICTION; CENTERS; CONSTRUCTION; ADSORPTION; SERIES; METALLOLIGANDS; NETWORKS;
D O I
10.1039/c2ce06692k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This highlight presents a review of porphyrin paddlewheel frameworks (PPFs) created using porphyrin metalloligands and paddlewheel secondary building units. The combination of these two components, along with dipyridyl pillaring linkers, results in the assembly of 25 PPFs. We describe the topology control exhibited in this series by considering the preferred coordination geometry of the porphyrin building blocks, the length and steric effects of the pillars, and the use of sequential self-assembly. These PPFs and related porphyrinic metal-organic frameworks are emerging as important materials for applications such as heterogeneous catalysis, gas storage, and light harvesting.
引用
收藏
页码:3839 / 3846
页数:8
相关论文
共 110 条
[1]   A NEW TYPE OF INFINITE 3D POLYMERIC NETWORK CONTAINING 4-CONNECTED, PERIPHERALLY LINKED METALLOPORPHYRIN BUILDING-BLOCKS [J].
ABRAHAMS, BF ;
HOSKINS, BF ;
ROBSON, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) :3606-3607
[2]   A Bioinspired Synthetic Approach for Building Metal-Organic Frameworks with Accessible Metal Centers [J].
Barron, Paul M. ;
Wray, Curtis A. ;
Hu, Chunhua ;
Guo, Zhiyong ;
Choe, Wonyoung .
INORGANIC CHEMISTRY, 2010, 49 (22) :10217-10219
[3]   Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins [J].
Barron, Paul M. ;
Son, Hyun-Tak ;
Hu, Chunhua ;
Choe, Wonyoung .
CRYSTAL GROWTH & DESIGN, 2009, 9 (04) :1960-1965
[4]   Anion-directed synthesis of metal-organic frameworks based on 2-picolinate Cu(II) complexes:: A ferromagnetic alternating chain and two unprecedented ferromagnetic fish backbone chains [J].
Biswas, Chaitali ;
Mukherjee, Pampa ;
Drew, Michael G. B. ;
Gomez-Garcia, Carlos J. ;
Clemente-Juan, Juan M. ;
Ghosh, Ashutosh .
INORGANIC CHEMISTRY, 2007, 46 (25) :10771-10780
[5]   Stepwise Synthesis of Metal-Organic Frameworks: Replacement of Structural Organic Linkers [J].
Burnett, Brandon J. ;
Barron, Paul M. ;
Hu, Chunhua ;
Choe, Wonyoung .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) :9984-9987
[6]   Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc [J].
Burrows, Andrew D. ;
Mahon, Mary F. ;
Wong, Claudia T. F. .
CRYSTENGCOMM, 2008, 10 (05) :487-489
[7]   Four new 2D porous polymeric frames from the self-assembly of silver triflate and silver tosylate with free-base and Zn-metallated 5,10,15,20-tetra(4-pyridyl)porphyrin [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM ;
Porta, F .
CRYSTENGCOMM, 2005, 7 :78-86
[8]   A new mixed-metal Mn-Rh coordination polymer assembled from Mn-containing molecular building blocks and Rh2(OAc)4 dimers [J].
Chapman, CT ;
Ciurtin, DM ;
Smith, MD ;
zur Loye, HC .
SOLID STATE SCIENCES, 2002, 4 (09) :1187-1191
[9]   Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material [J].
Chen, Banglin ;
Zhao, Xuebo ;
Putkham, Apipong ;
Hong, Kunlun ;
Lobkovsky, Emil B. ;
Hurtado, Eric J. ;
Fletcher, Ashleigh J. ;
Thomas, K. Mark .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6411-6423
[10]   Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules [J].
Chen, Banglin ;
Xiang, Shengchang ;
Qian, Guodong .
ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1115-1124