A convenient and improved synthesis of dithieno[3,2-b:2′,3′-d]thiophene

被引:54
作者
Allared, F [1 ]
Hellberg, J [1 ]
Remonen, T [1 ]
机构
[1] Royal Inst Technol, Dept Organ Chem, S-10044 Stockholm, Sweden
关键词
D O I
10.1016/S0040-4039(02)00006-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An improved synthesis of dithieno[3,2-b:2',3'- d]thiophene 1 is presented. By starting from in 2,3-dibromothiophene 2 the total yield as improved front 35 to 58%. We also describe a more convenient synthesis of one of the reagents. benzenesulfonic acid thioanhydride 3. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1553 / 1554
页数:2
相关论文
共 21 条
[1]  
BERTINELLI F, 1984, MOL CRYST LIQ CRYST, V109, P289, DOI 10.1080/00268948408078714
[2]   Palladium-catalyzed syntheses of polyethynyl-substituted 2,2'-bithiophenes [J].
Dahlmann, U ;
Neidlein, R .
HELVETICA CHIMICA ACTA, 1996, 79 (03) :755-766
[3]  
De Jong F, 1971, J ORG CHEM, V36, P1645
[4]  
DIMARCO P, 1985, MOL CRYST LIQ CRYST, V118, P241, DOI 10.1080/00268948508076217
[5]   HALOGEN-METAL INTERCONVERSION WITH DIBROMOBITHIENYLS [J].
GRONOWITZ, S .
ACTA CHEMICA SCANDINAVICA, 1961, 15 (06) :1393-&
[6]   THE X-RAY CRYSTAL-STRUCTURE OF A CHARGE-TRANSFER COMPLEX DERIVED FROM A NONPLANAR, BULKY, AND CONFORMATIONALLY FLEXIBLE DONOR COMPOUND [J].
HAYASHI, N ;
MAZAKI, Y ;
KOBAYASHI, K .
CHEMISTRY LETTERS, 1992, (09) :1689-1692
[7]   TETRAMETHYLDITHIENOTHIOPHENES - NEW DONORS FOR CATION-RADICAL SALTS [J].
HELLBERG, J ;
REMONEN, T .
SYNTHETIC METALS, 1995, 70 (1-3) :1137-1138
[8]   SELECTIVE FUNCTIONALIZATION OF 2,2'-BITHIOPHENES [J].
KHOR, E ;
SIU, CN ;
HWEE, CL ;
CHAI, S .
HETEROCYCLES, 1991, 32 (09) :1805-1812
[9]   New class of two-photon-absorbing chromophores based on dithienothiophene [J].
Kim, OK ;
Lee, KS ;
Woo, HY ;
Kim, KS ;
He, GS ;
Swiatkiewicz, J ;
Prasad, PN .
CHEMISTRY OF MATERIALS, 2000, 12 (02) :284-+
[10]   Photo/electroluminescent properties of novel bipolar oligomers [J].
Kim, OK ;
Woo, HY ;
Lee, KS ;
Kim, JK ;
Kim, DY ;
Shim, HK ;
Kim, CY .
SYNTHETIC METALS, 2001, 121 (1-3) :1607-1608