Asymmetric Friedel-Crafts reactions of vinyl ethers with fluoral catalyzed by chiral binaphthol-derived titanium catalysts

被引：32

作者：

Ishii, A ^{[1
]}

Mikami, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem Technol, Meguro Ku, Tokyo 1528552, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 97卷 / 1-2期

关键词：

Friedel-Crafts reaction; asymmetric catalysis; fluoral; vinyl ether;

D O I：

10.1016/S0022-1139(99)00025-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric Friedel-Crafts reactions of vinyl ethers with fluoral catalyzed by chiral binaphthol-derived titanium catalysts gave reactive vinyl ether products. Sequential diastereoselective reactions of resultant vinyl ethers with m-CPBA provided highly functionalized organofluorine compounds in high enantiomeric purity. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：51 / 55

页数：5

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