RECENT PROGRESS IN ORGANOCATALYTIC ASYMMETRIC HALOCYCLIZATION

被引：148

作者：

Murai, Kenichi ^{[1
]}

Fujioka, Hiromichi ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan

来源：

HETEROCYCLES | 2013年 / 87卷 / 04期

关键词：

Asymmetric Halocyclization; Organocatalyst; Enantioselective Halolactonization; gamma-Lactone; delta-Lactone; C-3-SYMMETRIC CHIRAL TRISIMIDAZOLINE; ONE-POT SYNTHESIS; ENANTIOSELECTIVE HALOCYCLIZATION; ELECTROPHILIC FLUORINATION; EFFICIENT SYNTHESIS; ANTIFUNGAL LACTONE; ACID-DERIVATIVES; CARBOXYLIC-ACIDS; DOMINO REACTION; C-3; SYMMETRY;

D O I：

10.3987/REV-12-762

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this review, recent progress made in the development of organocatalytic asymmetric halocyclization reactions that form heterocyclic compounds is described. New reactions and their mechanistic features are discussed in the context of an outline based on catalyst types, including biscinchona alkaloids, amino ureas, amino thioureas, amino thiocarbamates, chiral phosphoric acids, and trisimidazolines.

引用

页码：763 / +

页数：44

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