Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries

被引：446

作者：

Wang, Richard Y. ^{[1
]}

Wessells, Colin D. ^{[1
]}

Huggins, Robert A. ^{[1
]}

Cui, Yi ^{[1
,2
]}

机构：

[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA

[2] SLAC Natl Accelerator Lab, Stanford Inst Mat & Energy Sci, Menlo Pk, CA 94025 USA

来源：

NANO LETTERS | 2013年 / 13卷 / 11期

基金：

美国国家科学基金会;

关键词：

Ion insertion; magnesium ion batteries; aqueous batteries; Prussian Blue; open framework structure; nanomaterials; MIXED-VALENCE HEXACYANIDES; LONG CYCLE LIFE; PRUSSIAN-BLUE; COPPER HEXACYANOFERRATE; CHARGE-TRANSFER; ENERGY; INSERTION; NICKEL; CATHODE; SODIUM;

D O I：

10.1021/nl403669a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible insertion of monovalent ions such as lithium into electrode materials has enabled the development of rechargeable batteries with high energy density. Reversible insertion of divalent ions such as magnesium would allow the creation of new battery chemistries that are potentially safer and cheaper than lithium-based batteries. Here we report that nanomaterials in the Prussian Blue family of open framework materials, such as nickel hexacyanoferrate, allow for the reversible insertion of aqueous alkaline earth divalent ions, including Mg2+, Ca2+, Sr2+, and Ba2+. We show unprecedented long cycle life and high rate performance for divalent ion insertion. Our results represent a step forward and pave the way for future development in divalent batteries.

引用

页码：5748 / 5752

页数：5

共 47 条

[1] Investigation of yttrium and polyvalent ion intercalation into nanocrystalline vanadium oxide [J].

Amatucci, GG ;

Badway, F ;

Singhal, A ;

Beaudoin, B ;

Skandan, G ;

Bowmer, T ;

Plitza, I ;

Pereira, N ;

Chapman, T ;

Jaworski, R .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :A940-A950

[2] Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability [J].

Asakura, Daisuke ;

Okubo, Masashi ;

Mizuno, Yoshifumi ;

Kudo, Tetsuichi ;

Zhou, Haoshen ;

Ikedo, Kazumichi ;

Mizokawa, Takashi ;

Okazawa, Atsushi ;

Kojima, Norimichi .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (15) :8364-8369

[3] Prototype systems for rechargeable magnesium batteries [J].

Aurbach, D ;

Lu, Z ;

Schechter, A ;

Gofer, Y ;

Gizbar, H ;

Turgeman, R ;

Cohen, Y ;

Moshkovich, M ;

Levi, E .

NATURE, 2000, 407 (6805) :724-727

[4] Progress in rechargeable magnesium battery technology [J].

Aurbach, Doron ;

Suresh, Gurukar Shivappa ;

Levi, Elena ;

Mitelman, Ariel ;

Mizrahi, Oren ;

Chusid, Orit ;

Brunelli, Michela .

ADVANCED MATERIALS, 2007, 19 (23) :4260-+

[5] Thermally induced electron transfer in a CsCoFe Prussian blue derivative:: The specific role of the alkali-metal ion [J].

Bleuzen, A ;

Escax, V ;

Ferrier, A ;

Villain, F ;

Verdaguer, M ;

Münsch, P ;

Itié, JP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (28) :3728-3731

[6] CRYSTAL-STRUCTURE OF PRUSSIAN BLUE - FE4[FE(CN)6]3.XH2O [J].

BUSER, HJ ;

SCHWARZENBACH, D ;

PETTER, W ;

LUDI, A .

INORGANIC CHEMISTRY, 1977, 16 (11) :2704-2710

[7] Preparation, characterization, and electrocatalytic oxidation properties of iron, cobalt, nickel, and indium hexacyanoferrate [J].

Chen, SM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 521 (1-2) :29-52

[8] Lattice contractions and expansions accompanying the electrochemical conversions of Prussian blue and the reversible and irreversible insertion of rubidium and thallium ions [J].

Dostal, A ;

Kauschka, G ;

Reddy, SJ ;

Scholz, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 406 (1-2) :155-163

[9] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[10] ELECTROCHROMISM IN THE MIXED-VALENCE HEXACYANIDES .1. VOLTAMMETRIC AND SPECTRAL STUDIES OF THE OXIDATION AND REDUCTION OF THIN-FILMS OF PRUSSIAN BLUE [J].

ELLIS, D ;

ECKHOFF, M ;

NEFF, VD .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (09) :1225-1231

← 1 2 3 4 5 →