Rhodium-catalyzed and sonication-accelerated addition of aryltin and aryllead reagents to imines in air and water

被引：9

作者：

Ding, R

Zhao, CH

Chen, YJ

Liu, L

Wang, D ^{[1
]}

Li, CJ

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

[2] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 14期

基金：

中国国家自然科学基金;

关键词：

rhodium; imine addition; aqueous catalysis; air atmosphere; sonication;

D O I：

10.1016/j.tetlet.2004.01.160

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a rhodium catalyst, imines (1a-k) react with phenyltrimethyltin 2a or phenyltrimethyllead 2b in water and air under ultrasonic irradiation at 35 degreesC to give the corresponding diarylmethylamines (3a-k) in good yields. (C) 2004 Elsevier Ltd. All rights reserved.

引用

收藏

页码：2995 / 2998

页数：4

相关论文

共 37 条

[11]

GRIECO PA, 1998, ORGANIC SYNTHESIS

[12] Rhodium-catalyzed asymmetric arylation of imines with organostannanes. Asymmetric synthesis of diarylmethylamines [J].

Hayashi, T ;

Ishigedani, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) :976-977

[13] Quasi-nature catalysis. Rhodium-catalyzed C-C bond formation in air and water [J].

Huang, TS ;

Venkatraman, S ;

Meng, Y ;

Nguyen, TV ;

Kort, D ;

Wang, D ;

Ding, R ;

Li, CJ .

PURE AND APPLIED CHEMISTRY, 2001, 73 (08) :1315-1318

[14] Conjugate addition of arylsilanes to unsaturated carbonyl compounds catalyzed by rhodium in air and water [J].

Huang, TS ;

Li, CJ .

CHEMICAL COMMUNICATIONS, 2001, (22) :2348-2349

[15] Novel synthesis of α-amino acids via catalysis in air and water [J].

Huang, TS ;

Li, CJ .

ORGANIC LETTERS, 2001, 3 (13) :2037-2039

[16] Remarkable electronic effect on rhodium-catalyzed carbonyl additions and conjugated additions with arylmetallic reagents [J].

Huang, TS ;

Meng, Y ;

Venkatraman, S ;

Wang, D ;

Li, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (30) :7451-7452

[17] Catalytic enantioselective addition to imines [J].

Kobayashi, S ;

Ishitani, H .

CHEMICAL REVIEWS, 1999, 99 (05) :1069-1094

[18]

Li C. -J., 1997, ORGANIC REACTIONS AQ

[19] Quasi-nature catalysis: Developing C-C bond formations catalyzed by late transition metals in air and water [J].

Li, CJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :533-538

[20] Grignard-type carbonyl phenylation in water and under an air atmosphere [J].

Li, CJ ;

Meng, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (39) :9538-9539

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