Metal oxide nanowires for use in chemical sensing applications

被引:84
作者
Sawicka, KM [1 ]
Prasad, AK [1 ]
Gouma, PI [1 ]
机构
[1] SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11794 USA
关键词
metal oxide nanowires; tungsten oxide sensor; electrospinning; sol-gel;
D O I
10.1166/sl.2005.010
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The electrospinning technique was employed to produce nanofiber/nanowire structures of MoO3 and WO3, using metal oxide-sol-gel and polymer solution mixtures as precursors. The effect of variation of processing parameters and composition was studied and it was found that the diameter of these novel nanostructures decreases with increasing the sol-gel concentration and reducing the solution flow rate. A case study is presented where WO3 nanowires are used as NO2 gas sensing elements and are compared to sol-gel processed films of the same material. The nanowires-based elements make better sensors, as they exhibit improved gas sensitivity, faster response and lower gas detection limit that the sol-gel based elements.
引用
收藏
页码:31 / 35
页数:5
相关论文
共 17 条
[1]   Investigation on the O3 sensitivity properties of WO3 thin films prepared by sol-gel, thermal evaporation and r.f. sputtering techniques [J].
Cantalini, C ;
Wlodarski, W ;
Li, Y ;
Passacantando, M ;
Santucci, S ;
Comini, E ;
Faglia, G ;
Sberveglieri, G .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 64 (1-3) :182-188
[2]   Characterization of sol-gel prepared WO3 thin films as a gas sensor [J].
Cantalini, C ;
Atashbar, MZ ;
Li, Y ;
Ghantasala, MK ;
Santucci, S ;
Wlodarski, W ;
Passacantando, M .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1999, 17 (04) :1873-1879
[3]   Beaded nanofibers formed during electrospinning [J].
Fong, H ;
Chun, I ;
Reneker, DH .
POLYMER, 1999, 40 (16) :4585-4592
[4]  
Formhals A, 1934, United States patent US, Patent No. 1975504
[5]  
Gouma PI, 2003, REV ADV MATER SCI, V5, P147
[6]   GOLD-LOADED TUNGSTEN-OXIDE SENSOR FOR DETECTION OF AMMONIA IN AIR [J].
MAEKAWA, T ;
TAMAKI, J ;
MIURA, N ;
YAMAZOE, N .
CHEMISTRY LETTERS, 1992, (04) :639-642
[7]   A semiconducting metal oxide sensor array for the detection of NOx and NH3 [J].
Marquis, BT ;
Vetelino, JF .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 77 (1-2) :100-110
[8]   Reactively sputtered MoO3 films for ammonia sensing [J].
Prasad, AK ;
Gouma, PI ;
Kubinski, DJ ;
Visser, JH ;
Soltis, RE ;
Schmitz, PJ .
THIN SOLID FILMS, 2003, 436 (01) :46-51
[9]   Comparison of sol-gel and ion beam deposited MoO3 thin film gas sensors for selective ammonia detection [J].
Prasad, AK ;
Kubinski, DJ ;
Gouma, PI .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :25-30
[10]   MoO3 and WO3 based thin film conductimetric sensors for automotive applications [J].
Prasad, AK ;
Gouma, PI .
JOURNAL OF MATERIALS SCIENCE, 2003, 38 (21) :4347-4352