Side-chain functionalized polymers containing bipyridine coordination sites: Polymerization and metal-coordination studies

被引：57

作者：

Carlise, JR ^{[1
]}

Weck, M ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 12期

关键词：

bipyridine; coordination polymer; ROMP; transition metal chemistry; supramolecular structures;

D O I：

10.1002/pola.20134

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the ligands around the metal centers. These polymers are the first polynorbornenes containing a 2,2'-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials. (C) 2004 Wiley Periodicals, Inc.

引用

页码：2973 / 2984

页数：12

共 47 条

[31] SYNTHESES AND ACTIVITIES OF NEW SINGLE-COMPONENT, RUTHENIUM-BASED OLEFIN METATHESIS CATALYSTS
NGUYEN, ST
GRUBBS, RH
ZILLER, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9858 - 9859
[32] RING-OPENING METATHESIS POLYMERIZATION (ROMP) OF NORBORNENE BY A GROUP-VIII CARBENE COMPLEX IN PROTIC MEDIA
NGUYEN, ST
JOHNSON, LK
GRUBBS, RH
ZILLER, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (10) : 3974 - 3975
[33] Molecular architecture of cyclic nanostructures: use of co-ordination chemistry in the building of supermolecules with predefined geometric shapes
Olenyuk, B
Fechtenkotter, A
Stang, PJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (11): : 1707 - 1728
[34] Self-assembly in natural and unnatural systems
Philp, D
Stoddart, JF
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (11) : 1154 - 1196
[35] SELF-ASSEMBLY OF HETERONUCLEAR SUPRAMOLECULAR HELICAL COMPLEXES WITH SEGMENTAL LIGANDS
PIGUET, C
HOPFGARTNER, G
BOCQUET, B
SCHAAD, O
WILLIAMS, AF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) : 9092 - 9102
[36] Helicates and related metallosupramolecular assemblies: Toward structurally controlled and functional devices
Piguet, C
[J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 1999, 34 (04) : 361 - 391
[37] Complexes of silver(I), thallium(I), lead(II) and barium(II) with bis[3-(2-pyridyl)pyrazol-1-yl]phosphinate: One-dimensional helical chains and discrete mononuclear complexes
Psillakis, E
Jeffery, JC
McCleverty, JA
Ward, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (09): : 1645 - 1651
[38] New insights into the mechanism of ruthenium-catalyzed olefin metathesis reactions
Sanford, MS
Ulman, M
Grubbs, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (04) : 749 - 750
[39] Schubert US, 2002, ANGEW CHEM INT EDIT, V41, P2892, DOI 10.1002/1521-3773(20020816)41:16<2892::AID-ANIE2892>3.0.CO
[40] 2-6

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