bipyridine;
coordination polymer;
ROMP;
transition metal chemistry;
supramolecular structures;
D O I:
10.1002/pola.20134
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Monomers containing (trisbipyridine) ruthenium(II), (bisbipyridine) palladium(II), and heteroleptic ruthenium complexes were synthesized and polymerized via ruthenium-catalyzed ring-opening metathesis polymerization in nonpolar solvents. The solubility of the resulting polyelectrolytes in nonpolar solutions could be tuned by alkyl functionalization of the ligands around the metal centers. These polymers are the first polynorbornenes containing a 2,2'-bipyridine-based metal complex at each repeating unit and might be used in numerous applications, including luminescent and electroluminescent materials. (C) 2004 Wiley Periodicals, Inc.