Synthesis of H2SO4 doped polyaniline film by potentiometric method

被引:27
作者
D Gaikwad, P. [1 ]
Shirale, D. J. [1 ]
Gade, V. K. [1 ]
Savale, P. A. [1 ]
Kharat, H. J. [1 ]
Kakde, K. P. [1 ]
Hussaini, S. S. [1 ]
Dhumane, N. R. [1 ]
Shirsat, M. D. [1 ]
机构
[1] Marathwada Univ, Dept Phys, Aurangabad 431004, Maharashtra, India
关键词
aniline; electrolytes; electrochemical polymerization; four-probe technique;
D O I
10.1007/BF02704611
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
H2SO4 doped polyaniline films were synthesized in aqueous acidic media. The polyaniline film deposited on platinum electrode exhibits highest conductivity. The conductivity of each H2SO4 doped polyaniline sample was determined by the four-probe technique. The current-voltage curve exhibits that polyaniline sample has an ohmic behaviour. Experiments were conducted to establish the conductivity of the sample from room temperature to 110 degrees C. The current was set constant. It has been observed that at lower current as well as higher current conductivity of the polyaniline sample is due to the electrons transferred to the conduction band. It is observed that the concentration ratio of 0.2:1 of aniline and H2SO4 for synthesis of PANI film on platinum electrode shows good conductivity.
引用
收藏
页码:169 / 172
页数:4
相关论文
共 13 条
[1]   Comparative studies of solid-state synthesized polyaniline doped with inorganic acids [J].
Abdiryim, T ;
Xiao-Gang, Z ;
Jamal, R .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 90 (2-3) :367-372
[2]   Glucose oxidase electrodes of polyaniline, poly(o-toluidine) and their copolymer as a biosensor:: a comparative study [J].
Borole, DD ;
Kapadi, UR ;
Mahulikar, PP ;
Hundiwale, DG .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2004, 15 (06) :306-312
[3]   ELECTROACTIVE POLYANILINE FILMS [J].
DIAZ, AF ;
LOGAN, JA .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (01) :111-114
[4]   Application of polyaniline as enzyme based biosensor [J].
Gerard, M ;
Malhotra, BD .
CURRENT APPLIED PHYSICS, 2005, 5 (02) :174-177
[5]   Application of conducting polymers to biosensors [J].
Gerard, M ;
Chaubey, A ;
Malhotra, BD .
BIOSENSORS & BIOELECTRONICS, 2002, 17 (05) :345-359
[6]   Resolution enhancement of scanning four-point-probe measurements on two-dimensional systems [J].
Hansen, TM ;
Stokbro, K ;
Hansen, O ;
Hassenkam, T ;
Shiraki, I ;
Hasegawa, S ;
Boggild, P .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2003, 74 (08) :3701-3708
[7]   POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].
HUANG, WS ;
HUMPHREY, BD ;
MACDIARMID, AG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&
[8]  
Kadirgan F, 1998, TURK J CHEM, V22, P91
[9]   Polyaniline: A polymer with many interesting intrinsic redox states [J].
Kang, ET ;
Neoh, KG ;
Tan, KL .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (02) :277-324
[10]   SELF-DOPED POLYANILINES ELECTROCHEMICALLY ACTIVE IN NEUTRAL AND BASIC AQUEOUS-SOLUTIONS - ELECTROPOLYMERIZATION OF SUBSTITUTED ANILINES [J].
KARYAKIN, AA ;
STRAKHOVA, AK ;
YATSIMIRSKY, AK .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 371 (1-2) :259-265