Synthesis and structural studies of 1,1′-bis-amino-functionalized ferrocenes, ferrocene salts, and ferrocenium salts

被引：42

作者：

Bradley, S ^{[1
]}

Camm, KD ^{[1
]}

Liu, XM ^{[1
]}

McGowan, PC ^{[1
]}

Mumtaz, R ^{[1
]}

Oughton, KA ^{[1
]}

Podesta, TJ ^{[1
]}

Thornton-Pett, M ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 04期

关键词：

D O I：

10.1021/ic010821k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Having isolated and characterized a series of sodium cyclopentadienide salts, we have synthesized a number of 1,1'-bis-amino-functionalized ferrocenes, 1,1'-bis-amino-functionalized ferrocene salts, and 1,1'-bis-amino-functionalized ferrocenium salts. Among these are the first crystallographically characterized examples of cyclopentadienyl units containing (piperidin-N-ylethyl)- and (pyrid-2-ylmethyl)cyclopentadienyl side chains. In the cases of some of the ferrocenes, ferrocene salts, and ferrocenium salts, there are some interesting structural features in the solid state. These include C-(HN)-N-... and C-H(...)pi cloud interactions as well as N-(HO)-O-... and N-(HF)-F-... hydrogen bonds.

引用

页码：715 / 726

页数：12

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