Pendent aminoaklyl-substituted monocyclopentadienyltitanium compounds and their polymerization behavior

被引：78

作者：

Blais, MS ^{[1
]}

Chien, JCW ^{[1
]}

Rausch, MD ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 17期

关键词：

D O I：

10.1021/om980118c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new aminoalkyl-substituted monocyclopentadienyltitanium trichloride compounds have been prepared that contain pyridyl (2-picolyl), diisopropylaminoethyl, dimethylaminoethyl, and phenylethyl ligands. Incorporation of these pendent ligands to corresponding (cyclopentadienyl)triisopropoxytitanium and (indenyl)triisopropoxytitanium complexes are also described, The utility of these complexes for the polymerization of ethylene, propylene and styrene has been investigated.

引用

页码：3775 / 3783

页数：9

共 27 条

[1] PREPARATION AND SPECTROSCOPIC STUDY OF FUNCTIONALLY SUBSTITUTED CYCLOPENTADIENIDES OF THALLIUM(I), POTASSIUM, RHODIUM(I), AND IRIDIUM(I)
ARTHURS, M
ALDAFFAEE, HK
HASLOP, J
KUBAL, G
PEARSON, MD
THATCHER, P
CURZON, E
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11): : 2615 - 2619
[2] FUNCTIONALLY-SUBSTITUTED DERIVATIVES OF (ETA(5)-CYCLOPENTADIENYL)TRIISOPROPOXYTITANIUM AND (ETA(5)-CYCLOPENTADIENYL)TRICHLOROTITANIUM
BARRY, S
KUCHT, A
KUCHT, H
RAUSCH, MD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) : 195 - 199
[3] A NEW SYNTHETIC ROUTE TO FUNCTIONALLY-SUBSTITUTED (ETA(5)-CYCLOPENTADIENYL)DICARBONYLIRIDIUM COMPOUNDS
BLAIS, MS
RAUSCH, MD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 502 (1-2) : 1 - 8
[4] FORMATION AND REACTIVITY OF HALOGEN-DERIVATIVES OF (ETA-5-CYCLOPENTADIENYL)THALLIUM
CONWAY, BG
RAUSCH, MD
[J]. ORGANOMETALLICS, 1985, 4 (04) : 688 - 693
[5] {[2-(dimethylamino)ethyl]cyclopentadienyl} titanium complexes. Influence of the dimethylamino group in Ziegler-Natta polymerization catalysis
Flores, JC
Chien, JCW
Rausch, MD
[J]. MACROMOLECULES, 1996, 29 (25) : 8030 - 8035
[6] ([2-(DIMETHYLAMINO)ETHYL]CYCLOPENTADIENYL)TRICHLOROTITANIUM - A NEW-TYPE OF OLEFIN POLYMERIZATION CATALYST
FLORES, JC
CHIEN, JCW
RAUSCH, MD
[J]. ORGANOMETALLICS, 1994, 13 (11) : 4140 - 4142
[7] [1-(2-phenylethyl)-2,3,4,5-tetramethylcyclopentadienyl]-titanium compounds. Synthesis and their use for the syndiospecific polymerization of styrene
Flores, JC
Wood, JS
Chien, JCW
Rausch, MD
[J]. ORGANOMETALLICS, 1996, 15 (23) : 4944 - 4950
[8] (TRIFLUOROMETHYL)CYCLOPENTADIENIDE - A POWERFUL ELECTRON-WITHDRAWING LIGAND FOR TRANSITION-METAL COMPLEXES
GASSMAN, PG
WINTER, CH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) : 4228 - 4229
[9] CYCLIC AMINES AS INTRAMOLECULAR DONOR LIGANDS IN PI-COMPLEXES OF TITANIUM
HERRMANN, WA
MORAWIETZ, MJA
PRIERMEIER, T
MASHIMA, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 486 (1-2) : 291 - 295
[10] A FACILE SYNTHETIC ROUTE TO (ETA(5)-BENZOYLCYCLOPENTADIENYL)METAL COMPOUNDS
JONES, SS
RAUSCH, MD
BITTERWOLF, TE
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 450 (1-2) : 27 - 31

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