Triarylamine polymers by microwave-assisted polycondensation for use in organic field-effect transistors

被引:43
作者
Horie, Masaki [2 ]
Luo, Yi [2 ,3 ]
Morrison, John J. [2 ]
Majewski, Leszek A. [3 ]
Song, Aimin [3 ]
Saunders, Brian R. [1 ]
Turner, Michael L. [2 ]
机构
[1] Univ Manchester, Polymer Sci & Engn Grp, Sch Mat, Manchester M1 7HS, Lancs, England
[2] Univ Manchester, Sch Chem, Organ Mat Innovat Ctr, Manchester M13 9PL, Lancs, England
[3] Univ Manchester, Sch Elect & Elect Engn, Manchester M60 1QD, Lancs, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1039/b808840c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Triarylamine polymers can be rapidly assembled by microwave-assisted amination of aryldibromides. A series of polymers are reported with backbones containing 4,4'-biphenyl, 2.9-fluorene and 3,6-carbazole repeating units. These polymers have been used to fabricate organic field-effect transistors. The devices show very stable operation under ambient conditions and p-type mobilities up to 2.3 x 10(-3) cm(2) V-1 s(-1), close to the highest mobility reported to date for this class of amorphous semiconductors.
引用
收藏
页码:5230 / 5236
页数:7
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