Di-μ-iodo-1:2κ4I-bis(quinoline)-1κN,2κN-bis(triphenylphosphine)-1κP,2κP-dicopper(I)

被引：20

作者：

Jin, QH ^{[1
]}

Wang, YX

Xin, XL

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China

[2] Beijing Inst Light Ind, Dept Chem Engn, Beijing 100037, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S010827019801333X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [CuI(PPh3)(C9H7N)](2) or [Cu2I2(C9H7N)(2)(C18H15P)(2)], is an inversion-symmetric dimer with two Cu atoms each tetrahedrally coordinated to two I, one N and one P atom. The diamond-shaped central Cu2I2 group has longer I ... I [4.351 (1) Angstrom] and shorter Cu ... Cu distances [3.144 (1) Angstrom] than the X ... X (X = Br, I) and Cu ... Cu distances found in the related compounds [CuBr(PPh3)(C9H7N)](2) and [CuI(C9H7N)(2)](2).

引用

页码：341 / 343

页数：3

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