Achieving high density of adsorbed hydrogen in microporous metal organic frameworks

被引：128

作者：

Lee, JY

Pan, L

Kelly, SR

Jagiello, J

Emge, TJ

Li, J

机构：

[1] Rutgers State Univ, Dept Chem & Biol Chem, Piscataway, NJ 08854 USA

[2] Quantachrome Instruments, Boynton Beach, FL 33426 USA

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 22期

关键词：

D O I：

10.1002/adma.200500867

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two microporous; metal organic framework structures are shown to possess hydrogen uptake capacities reaching 1.74 and 1.98 wt.-% at 77 K (1, 2, see Figure). These give the highest adsorbed H-2 density reported thus far for metal-organic-based porous materials. The estimated pore volumes are 0.33 and 0.38 cm(3) g(-1) for 1 and 2.

引用

页码：2703 / +

页数：5

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