PCP-bis(phosphinite) pincer complexes:: new homogeneous catalysts for α-arylation of ketones

被引：53

作者：

Churruca, F ^{[1
]}

SanMartin, R ^{[1
]}

Tellitu, I ^{[1
]}

Domínguez, E ^{[1
]}

机构：

[1] Euskal Herriko Unibersitatea, Zientzia & Teknol Fak, Bilbao 48080, Spain

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 19期

关键词：

palladacycles; catalysis; pincer complexes; alpha-arylation;

D O I：

10.1016/j.tetlet.2006.03.040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new p-alkoxycarbonylated palladium bis(phosphinite) PCP pincer complexes are easily prepared and for the first time evaluated as homogeneous catalysts in alpha-arylation of ketone enolates. Apart from the total absence of phenyl-aryl exchange by-products and significantly low catalyst loadings, the general alpha-arylation protocols described in this letter feature not only a broad applicability to a range of ketones and aryl bromides with marked electronic and steric differences but also the possibility to generate mono-diarylated products. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：3233 / 3237

页数：5

共 35 条

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