1-Phosphabarrelene complexes of palladium and their use in Suzuki-Miyaura coupling reactions

被引：32

作者：

Blug, Matthias ^{[1
]}

Guibert, Clement ^{[1
]}

Le Goff, Xavier-Frederic ^{[1
]}

Mezailles, Nicolas ^{[1
]}

Le Floch, Pascal ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 02期

关键词：

N-HETEROCYCLIC CARBENE; ARYL CHLORIDES; ARYLBORONIC ACIDS; INTERNAL ALKENES; CROSS-COUPLINGS; PHOSPHININES; CATALYSTS; LIGANDS; NHC; HYDROFORMYLATION;

D O I：

10.1039/b814886d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bulky 1-phosphabarrelene, 2, was obtained from the reaction of a phosphinine with benzyne; two palladium complexes of 2 were successfully employed in the Suzuki-Miyaura coupling of several aryl chlorides with phenylboronic acid at a relatively low catalyst loading, and activated aryl chlorides were coupled at room temperature in the absence of strong bases.

引用

页码：201 / 203

页数：3

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