Involvement of intramolecular hydride transfer in the formation of alkanes from palladium alkyls

被引：24

作者：

Albeniz, AC ^{[1
]}

Espinet, P ^{[1
]}

Lin, YS ^{[1
]}

机构：

[1] UNIV VALLADOLID,FAC CIENCIAS,DEPT QUIM INORGAN,E-47005 VALLADOLID,SPAIN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 19期

关键词：

D O I：

10.1021/om9703651

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Intramolecular hydride transfer in a dimer between Pd atoms and reductiue elimination of H and a benzyl moiety to give PhCH2CH2C6F5 (3) is the main decomposition pathway for the hydrido species generated from the eta(3)-benzyEpalladium derivative [Pd-2(mu-Br)(2)(eta(3)-CHPhCH2C6F5)(2)] (1). The commonly accepted decomposition of the palladium hydride to give Pd(0) and HX, followed by acid attack on 1 to produce the alkane, is ruled out in this case.

引用

页码：4030 / 4032

页数：3

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