Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

被引：86

作者：

Nugent, Patrick ^{[1
]}

Rhodus, Vanessah ^{[1
]}

Pham, Tony ^{[1
]}

Tudor, Brant ^{[1
]}

Forrest, Katherine ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Space, Brian ^{[1
]}

Zaworotko, Michael ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 16期

关键词：

METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE CAPTURE; COORDINATION POLYMERS; INTERPENETRATION; DESIGN;

D O I：

10.1039/c3cc37695h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pillar substitution in a long-known metal-organic material with saturated metal centres, [Cu(bipy)(2)(SiF6)](n), has afforded the first crystallographically characterized porous materials based upon TiF62- and SnF62- anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N-2.

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收藏

页码：1606 / 1608

页数：3

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