The first structurally characterized coordination compound containing direct Al-Cr bonding:: Cp*Al-Cr(CO)5

被引：68

作者：

Yu, Q ^{[1
]}

Purath, A ^{[1
]}

Donchev, A ^{[1
]}

Schnöckel, H ^{[1
]}

机构：

[1] Univ Karlsruhe TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 584卷 / 01期

关键词：

aluminium(I) compounds; cyclopentadiene; Al-Cr bonding; crystal structure; chromiumpentacarbonyl;

D O I：

10.1016/S0022-328X(99)00100-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In order to investigate the bonding of the carbene-like ligand AlCp* towards a has been prepared starting from Cr(CO)SCOT and AlCp*. With the help of its cr ab initio calculations, the Al-Cr bonding is discussed. The strong reducing al towards the chromium atom and finally to the CO ligands. (C) 1993 Elsevier Science S.A. All rights reserved.

引用

页码：94 / 97

页数：4

共 36 条

[1] ELECTRONIC-STRUCTURE CALCULATIONS ON WORKSTATION COMPUTERS - THE PROGRAM SYSTEM TURBOMOLE [J].

AHLRICHS, R ;

BAR, M ;

HASER, M ;

HORN, H ;

KOLMEL, C .

CHEMICAL PHYSICS LETTERS, 1989, 162 (03) :165-169

[2] THE MOLECULAR-STRUCTURES OF BIS(PENTAMETHYLCYCLOPENTADIENYL)-CALCIUM AND BIS(PENTAMETHYLCYCLOPENTADIENYL)-YTTERBIUM IN THE GAS-PHASE - 2 BENT METALLOCENES [J].

ANDERSEN, RA ;

BONCELLA, JM ;

BURNS, CJ ;

BLOM, R ;

HAALAND, A ;

VOLDEN, HV .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 312 (03) :C49-C52

[3]

[Anonymous], 1996, ANGEW CHEM, V108, P141

[4]

DOHMEIER C, 1994, ANGEW CHEM INT EDIT, V33, P2482

[5] Aluminum(I) and gallium(I) compounds: Syntheses, structures, and reactions [J].

Dohmeier, C ;

Loos, D ;

Schnockel, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (02) :129-149

[6] THE TETRAMERIC ALUMINUM(I) COMPOUND [(AL(ETA-5-C5ME5))4] [J].

DOHMEIER, C ;

ROBL, C ;

TACKE, M ;

SCHNOCKEL, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05) :564-565

[7] DECAMETHYLALUMINOCENIUM, A PI-STABILIZED R(2)AL+ CATION [J].

DOHMEIER, C ;

SCHNOCKEL, H ;

ROBL, C ;

SCHNEIDER, U ;

AHLRICHS, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (11) :1655-1657

[8]

DOHMEIER C, 1994, ANGEW CHEM, V106, P2570

[9]

Dohmeier C., 1991, ANGEW CHEM, V103, P594

[10]

Ecker A, 1998, Z ANORG ALLG CHEM, V624, P513, DOI 10.1002/(SICI)1521-3749(199803)624:3<513::AID-ZAAC513>3.0.CO

← 1 2 3 4 →