Nitroxide-mediated polymerization

被引：1166

作者：

Nicolas, Julien ^{[1
]}

Guillaneuf, Yohann ^{[2
]}

Lefay, Catherine ^{[2
]}

Bertin, Denis ^{[2
]}

Gigmes, Didier ^{[2
]}

Charleux, Bernadette ^{[3
]}

机构：

[1] Univ Paris 11, Lab Physicochim Pharmacotech & Biopharm, CNRS, Fac Pharm,UMR 8612, F-92296 Chatenay Malabry, France

[2] Aix Marseille Univ, Inst Chim Radicalaire, CNRS, Fac St Jerome,UMR 7273, F-13397 Marseille 20, France

[3] Univ Lyon 1, Lab Chim Catalyse Polymeres & Proc C2P2, LCPP, CPE Lyon,CNRS,UMR 5265, F-69616 Villeurbanne, France

来源：

PROGRESS IN POLYMER SCIENCE | 2013年 / 38卷 / 01期

关键词：

Controlled/living radical polymerization; Nitroxide-mediated polymerization; Nitroxide; Alkoxyamine; Macromolecular architecture; Polymerization process; Kinetics; Polymerization in dispersed media; FREE-RADICAL POLYMERIZATION; N-BUTYL ACRYLATE; C-ON BOND; AMPHIPHILIC BLOCK-COPOLYMERS; RING-OPENING POLYMERIZATION; PARAMAGNETIC-RESONANCE SPECTROSCOPY; SPIN CAPTURING POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; ONE-POT SYNTHESIS; POLY(METHYL METHACRYLATE)/POLYSTYRENE BRUSHES;

D O I：

10.1016/j.progpolymsci.2012.06.002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization (CLRP) technique that enables the design of well-defined, functional and complex macromolecular architectures. This comprehensive review covers all aspects, features and achievements of NMP, from its discovery to 2012. All topics related to NMP are thoroughly discussed and detailed in-depth: synthetic approaches to nitroxides and alkoxyamines, kinetic aspects and polymerization features, range of controllable monomers, polymer characterization, polymerization processes (ionic liquids, dispersed media, etc.), macromolecular coupling approaches, functionalization strategies, macromolecular architectures, bio-related and hybrid materials, industrial applications as well as environmental constraints. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：63 / 235

页数：173

共 1204 条

[131] Controlled nitroxide-mediated and reversible addition-fragmentation chain transfer polymerization of N-vinylpyrrolidone:: Synthesis of block copolymers with styrene and 2-vinylpyridine [J].