Metal-Organic Frameworks Capable of Healing at Low Temperatures

被引：8

作者：

Chen, Ziguang ^{[1
]}

Wang, Gonghua ^{[1
]}

Xu, Zhanping ^{[1
]}

Li, Hui ^{[2
]}

Dhotel, Alexandre ^{[1
,3
,4
]}

Zeng, Xiao Cheng ^{[2
]}

Chen, Banglin ^{[5
]}

Saiter, Jean-Marc ^{[3
,4
]}

Tan, Li ^{[1
]}

机构：

[1] Univ Nebraska, Dept Mech & Mat Engn, Lincoln, NE 68588 USA

[2] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[3] Univ Rouen, Inst Mat, Int Lab, AMME LECAP,EA4528, F-76801 St Etienne, France

[4] INSA Rouen, F-76801 St Etienne, France

[5] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 42期

基金：

美国国家科学基金会;

关键词：

metal-organic frameworks; healing; welding; interfacial binding; low temperatures; POROUS POLYMER NETWORKS; HYDROGEN STORAGE; MESOPOROUS SILICA; DRUG-DELIVERY; GAS; MOLECULES; EXCHANGE; SITES;

D O I：

10.1002/adma.201302471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Filling crystalline gaps with small molecules can drive interfacial healing between anisotropic solids. Sufficient mobility from these fillers allows the process to happen at a low temperature of -56 °C. Mended bulk crystals show modulus leap from 4 to 12 GPa and hardness from 400 to 1000 MPa. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6106 / 6111

页数：6

共 39 条

[1] High-Throughput Fabrication of Uniform and Homogenous MOF Coatings [J].

Arslan, Hasan K. ;

Shekhah, Osama ;

Wohlgemuth, Jonas ;

Franzreb, Matthias ;

Fischer, Roland A. ;

Woell, Christof .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (22) :4228-4231

[2]

Bundschuh S., 2012, APPL PHYS LETT, P101

[3]

Callister W D., 2018, Materials Science and Engineering: An Introduction, V10th edn

[4]

Carné-Sánchez A, 2013, NAT CHEM, V5, P203, DOI [10.1038/NCHEM.1569, 10.1038/nchem.1569]

[5] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules [J].

Chen, Banglin ;

Ma, Shengqian ;

Zapata, Fatima ;

Fronczek, Frank R. ;

Lobkovsky, Emil B. ;

Zhou, Hong-Cai .

INORGANIC CHEMISTRY, 2007, 46 (04) :1233-1236

[6] Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks [J].

Cohen, Seth M. .

CHEMICAL REVIEWS, 2012, 112 (02) :970-1000

[7] Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal-Organic Frameworks [J].

Das, Sunirban ;

Kim, Hyunuk ;

Kim, Kimoon .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3814-+

[8] Functionalized Conjugated Microporous Polymers [J].

Dawson, Robert ;

Laybourn, Andrea ;

Clowes, Rob ;

Khimyak, Yaroslav Z. ;

Adams, Dave J. ;

Cooper, Andrew I. .

MACROMOLECULES, 2009, 42 (22) :8809-8816

[9] Large-Pore Apertures in a Series of Metal-Organic Frameworks [J].

Deng, Hexiang ;

Grunder, Sergio ;

Cordova, Kyle E. ;

Valente, Cory ;

Furukawa, Hiroyasu ;

Hmadeh, Mohamad ;

Gandara, Felipe ;

Whalley, Adam C. ;

Liu, Zheng ;

Asahina, Shunsuke ;

Kazumori, Hiroyoshi ;

O'Keeffe, Michael ;

Terasaki, Osamu ;

Stoddart, J. Fraser ;

Yaghi, Omar M. .

SCIENCE, 2012, 336 (6084) :1018-1023

[10] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].

Dinca, Mircea ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779

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