Highly enantioselective synthesis via dynamic kinetic resolution under transfer hydrogenation using Ru(η6-arene)-N-perfluorosulfonyl-1,2-diamine catalysts:: a first insight into the relationship of ligand's pKa and the catalyst activity

被引：93

作者：

Mohar, B

Valleix, A

Desmurs, JR

Felemez, M

Wagner, A ^{[1
]}

Mioskowski, C

机构：

[1] CEA, Serv Mol Marquees, F-91191 Gif Sur Yvette, France

[2] Natl Inst Chem, SI-1001 Ljubljana, Slovenia

[3] Rhodia Chim, F-69192 St Fons, France

[4] Fac Pharm, CNRS, UMR 7514, F-67401 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b107822b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

beta-(3,4-Dimethoxyphenyl)serine methyl ester was obtained in high diastereomeric and enantiomeric excesses under transfer hydrogenation using chiral Ru(eta (6)-arene)-N-perfluorosulfonyl-1,2-diamine catalysts.

引用

页码：2572 / 2573

页数：2

共 23 条

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