A new fluorogenic benzothiazolyl ionophore based upon calix[4]arene-crown-5 ether for calcium determination in aqueous media

被引：27

作者：

Kim, YH ^{[1
]}

Cha, NR ^{[1
]}

Chang, SK ^{[1
]}

机构：

[1] Chung Ang Univ, Dept Chem, Seoul 156756, South Korea

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 21期

关键词：

fluoroionophore; calix[4]-crown ether; benzothiazole; Ca2+-selectivity; aqueous media;

D O I：

10.1016/S0040-4039(02)00658-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new benzothiazolyl functionalized ionophore based upon the cafix[4]arene-crown-5 ether has been prepared and its fluoroionophoric properties toward Ca2+ ions were investigated. The compound exhibited a pronouncedly selective fluoroionophoric behavior toward Ca2+ ions were among those surveyed physiologically important metal ions of Na+. K+. and Mg2+. Detection limit for Ca2+ ions was found to be 9x10(-5) M in dioxane water (80:20. v.v) solution. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：3883 / 3886

页数：4

相关论文

共 22 条

[11] Calix[4]arenes bearing two distal Azophenol moieties:: Highly selective chromogenic ionophores for the recognition of Ca2+ ion [J].

Kim, NY ;

Chang, SK .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (07) :2362-2364

[12] Effective signal control (off-on-off action) by metal ionic inputs on a new chromoionophore-based calix[4]crown [J].

Kubo, Y ;

Obara, S ;

Tokita, S .

CHEMICAL COMMUNICATIONS, 1999, (23) :2399-2400

[13] A new family of indoaniline-derived calix[4]arenes: Synthesis and optical recognition properties as a chromogenic receptor [J].

Kubo, Y ;

Tokita, S ;

Kojima, Y ;

Osano, YT ;

Matsuzaki, T .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (11) :3758-3765

[14] FLUORESCENCE REACTIONS OF CROWNED BENZOTHIAZOLYLPHENOLS WITH ALKALI AND ALKALINE-EARTH METAL-IONS AND THEIR ANALYTICAL APPLICATIONS [J].

NAKASHIMA, K ;

NAGAOKA, Y ;

NAKATSUJI, S ;

KANEDA, T ;

TANIGAWA, I ;

HIROSE, K ;

MISUMI, S ;

AKIYAMA, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (09) :3219-3223

[15] MOLECULAR DESIGN OF CALIX[4]ARENE-BASED EXTRACTANTS WHICH SHOW HIGH CA2+ SELECTIVITY [J].

OGATA, M ;

FUJIMOTO, K ;

SHINKAI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) :4505-4506

[16]

RAWN JD, 1989, BIOCHEMISTRY-US, P1028

[17] A simple bifunctional fluoroionophore signaling different metal ions either independently or cooperatively [J].

Rurack, K ;

Koval'chuck, A ;

Bricks, JL ;

Slominskii, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (25) :6205-6206

[18] THE ATTRACTIONS OF PROTEINS FOR SMALL MOLECULES AND IONS [J].

SCATCHARD, G .

ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1949, 51 (04) :660-672

[19] Fluorescent fiber optic calcium sensor for physiological measurements [J].

Shortreed, M ;

Kopelman, R ;

Kuhn, M ;

Hoyland, B .

ANALYTICAL CHEMISTRY, 1996, 68 (08) :1414-1418

[20] SYNTHETIC MACROCYCLIC LIGANDS .6. LITHIUM ION-SELECTIVE FLUORESCENT EMISSION WITH CROWNED BENZO-THIAZOLYLPHENOL AND NAPHTHO-THIAZOLYLPHENOL [J].

TANIGAWA, I ;

TSUEMOTO, K ;

KANEDA, T ;

MISUMI, S .

TETRAHEDRON LETTERS, 1984, 25 (46) :5327-5330