High-Performance, Transparent, and Stretchable Electrodes Using Graphene-Metal Nanowire Hybrid Structures

被引:602
作者
Lee, Mi-Sun [1 ]
Lee, Kyongsoo [1 ]
Kim, So-Yun [1 ]
Lee, Heejoo [1 ]
Park, Jihun [1 ]
Choi, Kwang-Hyuk [2 ]
Kim, Han-Ki [2 ]
Kim, Dae-Gon [3 ]
Lee, Dae-Young [4 ]
Nam, SungWoo [5 ]
Park, Jang-Ung [1 ]
机构
[1] UNIST, Sch Nanobiosci & Chem Engn, Sch Mech & Adv Mat Engn, Low Dimens Carbon Mat Ctr, Ulsan 689798, South Korea
[2] Kyung Hee Univ, Dept Adv Mat Engn Informat & Elect, Yongin 446701, South Korea
[3] Samsung Techwin R&D Ctr, Songnam 463400, South Korea
[4] Samsung Display, Display Res Ctr, Yongin 446711, South Korea
[5] Univ Illinois, Dept Mech Sci & Engn, Urbana, IL 61801 USA
基金
新加坡国家研究基金会;
关键词
Nanowires; graphene; hybrid; transparent electrodes; stretchable electronics; FILMS; CONDUCTIVITY;
D O I
10.1021/nl401070p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transparent electrodes that can remain electrically conductive and stable under large mechanical deformations are highly desirable for applications in flexible and wearable electronics. This paper describes a comprehensive study of the electrical, optical, and mechanical properties of hybrid nanostructures based on two-dimensional graphene and networks of one-dimensional metal nanowires, and their use as transparent and stretchable electrodes. Low sheet resistance (33 Omega/sq) with high transmittance (94% in visible range), robust stability against electric breakdown and oxidation, and superb flexibility (27% in bending strain) and stretchability (100% in tensile strain) are observed, and these multiple functionalities of the hybrid structures suggest a future promise for next generation electronics The use of hybrid electrodes to fabricate oxide semiconductor, transistors and single-pixel displays integrated on wearable soft contact lenses with in vivo tests are demonstrated.
引用
收藏
页码:2814 / 2821
页数:8
相关论文
共 40 条
[1]   Spontaneous Formation of Periodic Nanostructures by Localized Dynamic Wrinkling [J].
Ahn, Se Hyun ;
Guo, L. Jay .
NANO LETTERS, 2010, 10 (10) :4228-4234
[2]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[3]   Impermeable atomic membranes from graphene sheets [J].
Bunch, J. Scott ;
Verbridge, Scott S. ;
Alden, Jonathan S. ;
van der Zande, Arend M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
NANO LETTERS, 2008, 8 (08) :2458-2462
[4]   LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].
BURROUGHES, JH ;
BRADLEY, DDC ;
BROWN, AR ;
MARKS, RN ;
MACKAY, K ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB .
NATURE, 1990, 347 (6293) :539-541
[5]   Nanopatterned Metallic Films for Use As Transparent Conductive Electrodes in Optoelectronic Devices [J].
Catrysse, Peter B. ;
Fan, Shanhui .
NANO LETTERS, 2010, 10 (08) :2944-2949
[6]   Intrinsic and extrinsic performance limits of graphene devices on SiO2 [J].
Chen, Jian-Hao ;
Jang, Chaun ;
Xiao, Shudong ;
Ishigami, Masa ;
Fuhrer, Michael S. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :206-209
[7]   Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy [J].
Chen, Shanshan ;
Brown, Lola ;
Levendorf, Mark ;
Cai, Weiwei ;
Ju, Sang-Yong ;
Edgeworth, Jonathan ;
Li, Xuesong ;
Magnuson, Carl W. ;
Velamakanni, Aruna ;
Piner, Richard D. ;
Kang, Junyong ;
Park, Jiwoong ;
Ruoff, Rodney S. .
ACS NANO, 2011, 5 (02) :1321-1327
[8]   The effects of percolation in nanostructured transparent conductors [J].
De, Sukanta ;
Coleman, Jonathan N. .
MRS BULLETIN, 2011, 36 (10) :774-781
[9]   Silver Nanowire Networks as Flexible, Transparent, Conducting Films: Extremely High DC to Optical Conductivity Ratios [J].
De, Sukanta ;
Higgins, Thomas M. ;
Lyons, Philip E. ;
Doherty, Evelyn M. ;
Nirmalraj, Peter N. ;
Blau, Werner J. ;
Boland, John J. ;
Coleman, Jonathan N. .
ACS NANO, 2009, 3 (07) :1767-1774
[10]  
Emtsev KV, 2009, NAT MATER, V8, P203, DOI [10.1038/nmat2382, 10.1038/NMAT2382]