Gold catalysis

被引：3233

作者：

Hashmi, A. Stephen K.

Hutchings, Graham J.

机构：

[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany

[2] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 47期

关键词：

gold; heterogeneous catalysis; homogeneous catalysis; promoters; supports;

D O I：

10.1002/anie.200602454

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalysis by gold has rapidly become a hot topic in chemistry, with a new discovery being made almost every week. Gold is equally effective as a heterogeneous or a homogeneous catalyst and in this Review we attempt to marry these two facets to demonstrate this new found and general efficacy of gold. The latest discoveries are placed within a historical context, but the main thrust is to highlight the new catalytic possibilities that gold-catalyzed reactions currently offer the synthetic chemist, in particular in redox reactions and nucleophilic additions to π systems. Indeed gold has proved to be an effective catalyst for many reactions for which a catalyst had not been previously identified, and many new discoveries are still expected. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7896 / 7936

页数：41

共 506 条

[31] AuCl3-catalyzed benzannulation:: Synthesis of naphthyl ketone derivatives from o-alkynylbenzaldehydes with alkynes [J].