One-dimensional μ-chloromanganese(II)-tetrathiafulvalene (TTF) coordination compound

被引：84

作者：

Jia, CY

Liu, SX

Ambrus, C

Neels, A

Labat, G

Decurtins, S

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[2] Univ Neuchatel, Inst Chem, CH-2007 Neuchatel, Switzerland

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 08期

关键词：

D O I：

10.1021/ic060056f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(mu-Cl)Cl-(1)(2)(CH3OH)],, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.

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页码：3152 / 3154

页数：3

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