π-σ-Phosphonic Acid Organic Monolayer/Sol-Gel Hafnium Oxide Hybrid Dielectrics for Low-Voltage Organic Transistors

被引:135
作者
Acton, Orb [1 ]
Ting, Guy [2 ]
Ma, Hong [1 ]
Ka, Jae Won [1 ]
Yip, Hin-Lap [1 ]
Tucker, Neil M. [2 ]
Jen, Alex K. -Y. [1 ,2 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
D O I
10.1002/adma.200800810
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Anthryl-alkyl-PA (pi-sigma-PA) self-assembled monolayers (SAMs)/hafnium oxide (HfO2) hybrid dielectrics have been integrated into organic thin film transistors (OTFTs) to achieve operating voltages under -1.5V. Using pi-sigma-PA SAMs on sol-gel processed HfO2, pentacene-based OTFTs possess low subthreshold slopes (100 mV dec(-1)), high on-off current ratios (10(5)-10(6)), and hole mobilities as high as 0.22 cm(2) V-(1) s(-1).
引用
收藏
页码:3697 / +
页数:6
相关论文
共 46 条
[1]   Functionalized acenes and heteroacenes for organic electronics [J].
Anthony, John E. .
CHEMICAL REVIEWS, 2006, 106 (12) :5028-5048
[2]   Sol-gel fabrication of dielectric HfO2 nano-films;: Formation of uniform, void-free layers and their superior electrical properties [J].
Aoki, Y ;
Kunitake, T ;
Nakao, A .
CHEMISTRY OF MATERIALS, 2005, 17 (02) :450-458
[3]   Ambipolar charge transport in air-stable polymer blend thin-film transistors [J].
Babel, A ;
Wind, JD ;
Jenekhe, SA .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (09) :891-898
[4]   Suppression of charge carrier tunneling through organic self-assembled monolayers [J].
Boulas, C ;
Davidovits, JV ;
Rondelez, F ;
Vuillaume, D .
PHYSICAL REVIEW LETTERS, 1996, 76 (25) :4797-4800
[5]   General observation of n-type field-effect behaviour in organic semiconductors [J].
Chua, LL ;
Zaumseil, J ;
Chang, JF ;
Ou, ECW ;
Ho, PKH ;
Sirringhaus, H ;
Friend, RH .
NATURE, 2005, 434 (7030) :194-199
[6]   Low-voltage, 30 nm channel length, organic transistors with a self-assembled monolayer as gate insulating films [J].
Collet, J ;
Tharaud, O ;
Chapoton, A ;
Vuillaume, D .
APPLIED PHYSICS LETTERS, 2000, 76 (14) :1941-1943
[7]   Large-scale complementary integrated circuits based on organic transistors [J].
Crone, B ;
Dodabalapur, A ;
Lin, YY ;
Filas, RW ;
Bao, Z ;
LaDuca, A ;
Sarpeshkar, R ;
Katz, HE ;
Li, W .
NATURE, 2000, 403 (6769) :521-523
[8]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[9]  
2-9
[10]   Gate dielectrics for organic field-effect transistors: New opportunities for organic electronics [J].
Facchetti, A ;
Yoon, MH ;
Marks, TJ .
ADVANCED MATERIALS, 2005, 17 (14) :1705-1725