Oxidations catalyzed by zeolite ship-in-a-bottle complexes

被引：133

作者：

Balkus, KJ ^{[1
]}

Khanmamedova, AK ^{[1
]}

Dixon, KM ^{[1
]}

Bedioui, F ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM,LAB ELECTROCHIM & CHIM ANALYT,URA CNRS 216,F-75231 PARIS 05,FRANCE

来源：

APPLIED CATALYSIS A-GENERAL | 1996年 / 143卷 / 01期

关键词：

zeolites; ship-in-a-bottle complexes; oxidations; V(O)SALEN; RuF(16)Pc;

D O I：

10.1016/0926-860X(96)00078-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A brief review of oxidation reactions catalyzed by zeolite ship-in-a-bottle complexes is presented. The encapsulation of V(O)SALEN (SALEN = bis(salicylaldehyde)ethylenediimine) in zeolite NaY via the flexible ligand method is described. V(O)SALEN-NaY was found to be an effective catalyst for the room temperature epoxidation of cyclohexene using t-butylhydroperoxide (t-BOOH) as the oxidant. The preparation of zeolite NaX in the presence of RuF(16)Pc (F(16)Pc = perfluorophthalocyanine) also results in occluded metal complex. RuF(16)Pc-NaX has been shown to be an active catalyst for the room temperature oxidation of alkanes using t-BOOH as the oxidant.

引用

页码：159 / 173

页数：15

共 45 条

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