A novel 3D coordination polymer [Cd15([μ4-Mtta)12(μ3-Mtta)6(μ3-SO4)4(μ3-OH)4]: Synthesis, structure and solid properties

被引：11

作者：

Ding, You-Bang ^{[1
]}

Cheng, Ying ^{[1
]}

Zhang, Zhi-Ling ^{[1
]}

Zhang, Jing ^{[1
]}

Yin, Ye-Gao ^{[1
]}

Gao, Wen-Hua ^{[1
]}

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 01期

关键词：

Cadmium (II); Tetrazole; Coordination polymer; In situ synthesis; Fluorescence; HYDROTHERMAL SYNTHESIS; PHYSICAL-PROPERTIES; TETRAZOLE FORMATION; NITRILES; TETRANUCLEAR; COMPLEXES; LIGANDS; AZIDE;

D O I：

10.1016/j.inoche.2008.11.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D coordination polymer, {[Cd-15(mu(4)-Mtta)(12)(mu(3)-Mtta)(6)(mu(3)-SO4)(4)(mu(3)-OH)(4)] center dot 6H(2)O]}(n) (1) (Mtta = 5-methyl-tetrazolate), which shows the rare multifunction of in situ formed Mtta and bright photo-induced blue emission, was isolated from a hydrothermal reaction of CdSO4 center dot 8/3H(2)O, NaN3 in acetonitrile and water. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：45 / 47

页数：3

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