Biaryl phosphane ligands in palladium-catalyzed amination

被引:1804
作者
Surry, David S. [1 ]
Buchwald, Stephen L. [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
基金
美国国家卫生研究院;
关键词
coupling reactions; heterocycles; homogeneous catalysis; palladium; phophane ligands;
D O I
10.1002/anie.200800497
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses the application of these catalysts in C-N cross-coupling reactions in the synthesis of heterocycles and pharmaceuticals, in materials science, and in natural product synthesis. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6338 / 6361
页数:24
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