New lactone synthesis using a chromium carbene complex

被引：29

作者：

Ishibashi, T ^{[1
]}

Ochifuji, N ^{[1
]}

Mori, M ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 34期

关键词：

D O I：

10.1016/0040-4039(96)01338-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new lactone synthesis was developed using the Fischer chromium carbene complex. The lactone was formed from an alkyne bearing a hydroxyl or silyloxyl group in a tether, along with carbene carbon and carbon monoxide of the chromium carbene complex. Using this procedure, (+)-blastmycinone and (+)-antimycinone were synthesized from (S)-ethyl lactate in short steps. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：6165 / 6168

页数：4

共 16 条

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