Controlled degradation of a magnesium alloy in simulated body fluid using hydrofluoric acid treatment followed by polyacrylonitrile coating

被引:33
作者
da Conceicao, Thiago F. [1 ]
Scharnagl, Nico [2 ,3 ]
Dietzel, Wolfgang [1 ]
Kainer, Karl U. [1 ]
机构
[1] Helmholtz Zentrum Geesthacht GmbH, Inst Mat Res, D-21502 Geesthacht, Germany
[2] Helmholtz Zentrum Geesthacht, Ctr Biomat Dev, D-14513 Teltow, Germany
[3] Helmholtz Zentrum Geesthacht, Berlin Brandenburg Ctr Regenerat Therapies BCRT, D-14513 Teltow, Germany
关键词
Magnesium; EIS; Polymer coatings; IMPLANTS; CORROSION; ULTRAFILTRATION; BIODEGRADATION; MEMBRANES; FORMAMIDE; SURFACE;
D O I
10.1016/j.corsci.2012.04.041
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
This paper describes the protection mechanism of polyacrylonitrile coatings on a hydrofluoric acid treated magnesium alloy. The protective performance of the adopted methodology was investigated by electrochemical impedance spectroscopy and immersion tests in 3.5 wt.% NaCl and in simulated body fluid (SBF). It was observed that interfacial reactions and interactions between polymer and substrate rendered long-term protection for the metal. A detailed characterization of the coating properties and of the interfacial processes is provided and the potential of the adopted methodology for biomedical application is discussed. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:83 / 89
页数:7
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