Chiral analysis of pollutants and their metabolites by capillary electromigration methods

被引:34
作者
Hernández-Borges, J
Rodríguez-Delgado, MA
García-Montelongo, FJ
Cifuentes, A
机构
[1] CSIC, Dept Food Anal, Inst Ind Fermentat, E-28006 Madrid, Spain
[2] Univ La Laguna, Dept Analyt Chem & Nutr & Food Sci, E-38207 San Cristobal la Laguna, Tenerife, Spain
关键词
CE; CEC; chiral analysis; enantiomers; MEKC; pesticides; pollutants; review;
D O I
10.1002/elps.200500084
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Chiral separation of enantiomers is one of the most challenging tasks for any analytical technique including CE. Since the first report in 1985 showing the great possibilities of CE for the separation of chiral compounds, the amount of publications concerning this topic has quickly increased. Although chiral electromigration methods have mainly been used for enantioseparation of drugs and pharmaceuticals, they have also been applied to analyze chiral pollutants. This article intends to provide an updated overview, including works published till January 2005, on the principal applications of CE to the chiral analysis of pollutants and their metabolites, with especial emphasis on articles published in the last 10 years. The main advantages and drawbacks regarding the use of CE for chiral separation of pollutants are addressed including some discussion on the foreseen trends of electromigration procedures applied to chiral analysis of contaminants.
引用
收藏
页码:3799 / 3813
页数:15
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