Isobaric-isothermal fluctuation theorem

被引：11

作者：

Mittag, E ^{[1
]}

Searles, DJ

Evans, DJ

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

[2] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia

来源：

JOURNAL OF CHEMICAL PHYSICS | 2002年 / 116卷 / 16期

关键词：

D O I：

10.1063/1.1462043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fluctuation theorem (FT) gives an analytical expression for the probability that in a finite nonequilibrium system observed for a finite time, the Second Law of Thermodynamics is violated. Since FT deals with fluctuations, the precise form of the theorem is dependent on the particular statistical mechanical ensemble. In the present paper we describe the application of the FT to the isothermal-isobaric ensemble. (C) 2002 American Institute of Physics.

引用

页码：6875 / 6879

页数：5

共 9 条

[1]

Evans D.J., 1990, STAT MECH NONEQUILIB

[2] PROBABILITY OF 2ND LAW VIOLATIONS IN SHEARING STEADY-STATES [J].

EVANS, DJ ;

COHEN, EGD ;

MORRISS, GP .

PHYSICAL REVIEW LETTERS, 1993, 71 (15) :2401-2404

[3] Fluctuation theorem for Hamiltonian systems: Le Chatelier's principle [J].

Evans, DJ ;

Searles, DJ ;

Mittag, E .

PHYSICAL REVIEW E, 2001, 63 (05)

[4] EQUILIBRIUM MICROSTATES WHICH GENERATE 2ND LAW VIOLATING STEADY-STATES [J].

EVANS, DJ ;

SEARLES, DJ .

PHYSICAL REVIEW E, 1994, 50 (02) :1645-1648

[5] DYNAMICAL ENSEMBLES IN NONEQUILIBRIUM STATISTICAL-MECHANICS [J].

GALLAVOTTI, G ;

COHEN, EGD .

PHYSICAL REVIEW LETTERS, 1995, 74 (14) :2694-2697

[6] Pressure of fluids and solids composed of particles interacting with a short-range repulsive potential [J].

Hess, S ;

Kröger, M .

PHYSICAL REVIEW E, 2000, 61 (04) :4629-4631

[7] Ensemble dependence of the transient fluctuation theorem [J].

Searles, DJ ;

Evans, DJ .

JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (09) :3503-3509

[8] The fluctuation theorem and Green-Kubo relations [J].

Searles, DJ ;

Evans, DJ .

JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (22) :9727-9735

[9]

Searles DJ, 2000, AIP CONF PROC, V519, P271, DOI 10.1063/1.1291568

← 1 →