Cleavage of immobilized disubstituted triazenes with electrophiles:: solid-phase synthesis of alkyl halides and esters

被引：19

作者：

Pilot, C

Dahmen, S

Lauterwasser, F

Bräse, S

机构：

[1] Univ Bonn, Kekule Inst Organ Chem & Biochim, D-53121 Bonn, Germany

[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(01)02019-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient, selective cleavage of polymer-bound disubstituted triazenes with trimethylsilyl halides produces alkyl chlorides, bromides and iodides in good to excellent purities and yields. Similarly. alkyl esters are formed upon cleavage with carboxylic acids. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：9179 / 9181

页数：3

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