FeCl3-Catalyzed Reduction of Ketones and Aldehydes to Alkane Compounds

被引：34

作者：

Dal Zotto, Christophe ^{[1
]}

Virieux, David ^{[1
]}

Campagne, Jean-Marc ^{[1
]}

机构：

[1] ENSCM, Inst Charles Gerhardt Montpellier, F-34296 Montpellier, France

来源：

SYNLETT | 2009年 / 02期

关键词：

iron; reduction; ketones; IRON-CATALYZED HYDROSILYLATION; METAL; POLYMETHYLHYDROSILOXANE;

D O I：

10.1055/s-0028-1087664

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketones can efficiently be reduced to the corresponding methylene compound using the convenient and inexpensive combination of PMHS and FeCl3.

引用

页码：276 / 278

页数：3

共 20 条

[1]

BART SC, 2008, ORG LETT, V10, P2789

[2] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[3]

Brunner H., 1991, J. Organomet. Chem, V412, P11

[4] Rapid defunctionalization of carbonyl group to methylene with polymethylhydrosiloxane-B(C6F5)3 [J].

Chandrasekhar, S ;

Reddy, CR ;

Babu, BN .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (25) :9080-9082

[5] Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes [J].

Correa, Arkaitz ;

Mancheno, Olga Garcia ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (06) :1108-1117

[6]

Dal Zotto C., 2008, SYNLETT, P2033, DOI DOI 10.1055/S-2008-1077954

[7] Sustainable metal catalysis with iron: From rust to a rising star? [J].

Enthaler, Stephan ;

Junge, Kathrin ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3317-3321

[8] A cheap metal for a "Noble" task:: Preparative and mechanistic aspects of cycloisomerization and cycloaddition reactions catalyzed by low-valent iron complexes [J].

Fuerstner, Alois ;

Majima, Keisuke ;

Martin, Ruben ;

Krause, Helga ;

Kattnig, Egmont ;

Goddard, Richard ;

Lehmann, Christian W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (06) :1992-2004

[9] Highly efficient catalytic system for hydrosilylation of ketones with iron(II) acetate-thiophenecarboxylate [J].

Furuta, Akihiro ;

Nishiyama, Hisao .

TETRAHEDRON LETTERS, 2008, 49 (01) :110-113

[10] A novel B(C6F5)3-catalyzed reduction of alcohols and cleavage of aryl and alkyl ethers with hydrosilanes [J].

Gevorgyan, V ;

Rubin, M ;

Benson, S ;

Liu, JX ;

Yamamoto, Y .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (19) :6179-6186

← 1 2 →