Highly efficient catalytic system for hydrosilylation of ketones with iron(II) acetate-thiophenecarboxylate

被引：58

作者：

Furuta, Akihiro ^{[1
]}

Nishiyama, Hisao ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Nagoya, Aichi 464, Japan

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 01期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.tetlet.2007.11.002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A combination of a catalyst derived from ferrous acetate and sodium thiophene-2-carboxylate efficiently promoted hydrosilylation of aromatic and aliphatic ketones to give the corresponding secondary alcohols in high yields with extremely high selectivity. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：110 / 113

页数：4

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