An iron-catalysed hydrosilylation of ketones

被引:206
作者
Nishiyama, Hisao [1 ]
Furuta, Akihiro [1 ]
机构
[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
D O I
10.1039/b617388h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The combination of Fe(OAc)(2) and multi-nitrogen-based ligands such as N,N, N', N'-tetramethyethylenediamine, bis-tert-butyl-bipyridine, or bis(oxazolinyl) pyridine can efficiently catalyse hydrosilylation of ketones to give the corresponding alcohols in high yields including asymmetric catalysis.
引用
收藏
页码:760 / 762
页数:3
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