Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol

被引：75

作者：

Bette, V

Mortreux, A

Lehmann, CW

Carpentier, JF

机构：

[1] Univ Lille 1, ENSCL, CNRS, UPRESA Chim Organ Appl 8010, F-59652 Villeneuve Dascq, France

[2] Max Planck Inst Kohlenforsch, D-45466 Mulheim, Germany

[3] Univ Rennes 1, Inst Chim, CNRS, UMR Organomet & Catalyse 6509, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 03期

关键词：

D O I：

10.1039/b210144k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ketones and imines are chemoselectively reduced at room temperature in methanol to the corresponding alcohols and amines in high yields in a one-step procedure using polymethylhydrosiloxane (PMHS) and a simple zinc-diamine catalyst.

引用

页码：332 / 333

页数：2

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