Highly regioselective ring opening of epoxides and aziridines using (bromodimethyl)sulfonium bromide

被引：59

作者：

Das, Biswanath ^{[1
]}

Krishnaiah, Maddeboina ^{[1
]}

Venkateswarlu, Katta ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 26期

关键词：

epoxide; aziridine; (bromodimethyl)sulfonium bromide; regioselectivity;

D O I：

10.1016/j.tetlet.2006.04.059

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxides and aziridines undergo ring opening efficiently with (bromodimethyl)sulfonium bromide at room temperature to form the corresponding beta-bromohydrins and beta-bromoamines, respectively. The conversions are highly regioselective and afford the products in excellent yields within a short period of time. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4457 / 4460

页数：4

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