A diprotonated hexatungstoplatinate(IV), Na6[H2PtW6O24]•22H2O

被引：8

作者：

Lee, U

Joo, HC

Park, KM

机构：

[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea

[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Chinju 660701, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804004970

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The novel protonated hexasodium dihydrogen hexatungstoplatinate(IV) doicosahydrate, Na-6[H2PtW6O24].22H(2)O, was crystallized in the triclinic system in space group P (1) over bar. The [H2PtW6O24](6-) polyanion has C-i ((1) over bar) symmetry. The identification of the protonated O atom in the polyanion is difficult because it does not form interpolyanion hydrogen bonds, and a clear difference was not found in the W-O(H) bond lengths or the W-O(H)-W bond angles to indicate protonation of the O atom.

引用

页码：I55 / I57

页数：3

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