Electroorganic reaction in ionic liquids. Part 1: Electrolytic partial fluorination of organic compounds. Part 58. Electroorganic synthesis under solvent-free conditions. Highly regioselective anodic monofluorination of cyclic ethers, lactones, and a cyclic carbonate

被引：52

作者：

Hasegawa, M ^{[1
]}

Ishii, H ^{[1
]}

Fuchigami, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(02)00047-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Regioselective anodic fluorination of cyclic ethers, lactones, and a cyclic carbonate in Et4NF.nHF (n = 4, 5) and Et3N.5HF without a solvent was successfully carried out to give the corresponding monofluorinated products in moderate yields. This is the first report of direct electochemical fluorination of cyclic ethers, lactones, and a cyclic carbonate using anodic fluorination. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：1503 / 1505

页数：3

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