Antiferrodistortive reconstruction of the PbTiO3(001) surface -: art. no. 016101

被引：66

作者：

Munkholm, A

Streiffer, SK

Murty, MVR

Eastman, JA

Thompson, C

Auciello, O

Thompson, L

Moore, JF

Stephenson, GB

机构：

[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

[3] No Illinois Univ, Dept Phys, De Kalb, IL 60115 USA

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 88卷 / 01期

关键词：

D O I：

10.1103/PhysRevLett.88.016101

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We present in situ x-ray scattering measurements of the surface structures of PbTiO3 (001) in equilibrium with PbO vapor. At 875 to 1025 K, a reconstruction having c(2 x 2) symmetry is present under most conditions, while a 1 x 6 reconstruction occurs under PbO-poor conditions. The atomic structure of the c(2 x 2) phase is found to consist of a single layer of an antiferrodistortive structure with oxygen cages counter-rotated by 10degrees about the titanium ions.

引用

页码：4 / 161014

页数：4

共 28 条

[21] FERROELECTRIC MONOLAYER RECONSTRUCTION OF THE SRTIO3 (100) SURFACE [J].