Bisrubescensins A-C:: Three new dimeric ent-kauranoids isolated from Isodon rubescens

被引：52

作者：

Huang, SX ^{[1
]}

Xiao, WL

Li, LM

Li, SH

Zhou, Y

Ding, LS

Lou, LG

Sun, HD

机构：

[1] Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Biol Sci, Shanghai Inst Mat Med, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 06期

关键词：

D O I：

10.1021/ol0531379

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A phytochemical study of the secondary metabolites produced by the species of Isodon rubescens has led to the isolation of three new dimeric ent-kauranoids and two known ones. The most important of these compounds are bisrubescensin A (1), which contains an unprecedented C-23 ent-kaurane unit, and bisrubescensin C (3), which is the precursor of bisrubescensin B (2) from the viewpoint of biosynthesis. Their structures were determined on the basis of extensive spectroscopic analysis and chemical evidence.

引用

页码：1157 / 1160

页数：4

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