Ni-Fe/Sm-doped CeO2 anode for ammonia-fueled solid oxide fuel cells

被引：49

作者：

Akimoto, Wataru ^{[1
]}

Fujimoto, Tadashi ^{[1
]}

Saito, Morihiro ^{[1
]}

Inaba, Minoru ^{[1
]}

Yoshida, Hiroyuki ^{[2
]}

Inagaki, Toru ^{[2
]}

机构：

[1] Doshisha Univ, Dept Mol Chem & Biochem, Kyotanabe, Kyoto 6100321, Japan

[2] Kansai Elect Power Co Inc, Energy Use R&D Ctr, Amagasaki, Hyogo 6610974, Japan

来源：

SOLID STATE IONICS | 2014年 / 256卷

关键词：

Solid oxide fuel cell; Ammonia fuel; Anode cermet; Ni-Fe alloy; Sm-doped ceria; PROTON CONDUCTING ELECTROLYTE; PERFORMANCE;

D O I：

10.1016/j.ssi.2013.12.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Anode cermets using various transition metals (Ni, Co, and Fe) and Ce0.8Sm0.2O2-sigma (SDC) were prepared and their catalytic activity for ammonia oxidation in solid oxide fuel cells (SOFCs) was investigated. Ni/SDC showed a high activity for hydrogen, but not for ammonia. Co/SDC showed a poor activity for both hydrogen and ammonia. Fe/SDC has the highest activity for ammonia oxidation in the temperature range of 973 to 1173 K. Moreover, it was found that Ni-Fe alloy/SDC anodes showed improved performance for ammonia oxidation. Ni40-Fe60/SDC anode showed the highest catalytic activity for NH3 oxidation, and therefore is promising for ammonia-fueled SOFCs. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：1 / 4

页数：4

共 17 条

[1]

Fabrication and study on Ni1-xFexO-YSZ anodes for intermediate temperature anode-supported solid oxide fuel cells [J].

Ding, Jiao ;

Liu, Jiang ;

Guo, Weimin .

JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 480 (02) :286-290

[2]

Conceptual design of a novel ammonia-fuelled portable solid oxide fuel cell system [J].

Farhad, Siamak ;

Hamdullahpur, Feridun .

JOURNAL OF POWER SOURCES, 2010, 195 (10) :3084-3090

[3]

Ammonia as efficient fuel for SOFC [J].

Fuerte, A. ;

Valenzuela, R. X. ;

Escudero, M. J. ;

Daza, L. .

JOURNAL OF POWER SOURCES, 2009, 192 (01) :170-174

[4]

DOPED LAGAO3 PEROVSKITE-TYPE OXIDE AS A NEW OXIDE IONIC CONDUCTOR [J].

ISHIHARA, T ;

MATSUDA, H ;

TAKITA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) :3801-3803

[5]

Fe alloying effect on the performance of the Ni anode in hydrogen fuel [J].

Lu, X. C. ;

Zhu, J. H. ;

Bi, Z. H. .

SOLID STATE IONICS, 2009, 180 (2-3) :265-270

[6]

A high-performance ammonia-fueled SOFC based on a YSZ thin-film electrolyte [J].

Ma, Qianli ;

Ma, Jianjun ;

Zhou, Sa ;

Yan, Ruiqiang ;

Gao, Jianfeng ;

Meng, Guangyao .

JOURNAL OF POWER SOURCES, 2007, 164 (01) :86-89

[7]

A high-performance ammonia-fueled solid oxide fuel cell [J].

Ma, Qianli ;

Peng, Ranran ;

Lin, Yongjing ;

Gao, Hanfeng ;

Meng, Guangyao .

JOURNAL OF POWER SOURCES, 2006, 161 (01) :95-98

[8]

A high performance direct ammonia fuel cell using a mixed ionic and electronic conducting anode [J].

Maffei, N. ;

Pelletier, L. ;

McFarlan, A. .

Journal of Power Sources, 2008, 175 (01) :221-225

[9]

A direct ammonia fuel cell using barium cerate proton conducting electrolyte doped with gadolinium and praseodymium [J].

Maffei, N. ;

Pelletier, L. ;

Charland, J. P. ;

McFarlan, A. .

FUEL CELLS, 2007, 7 (04) :323-328

[10]

An intermediate temperature direct ammonia fuel cell using a proton conducting electrolyte [J].

Maffei, N ;

Pelletier, L ;

Charland, JP ;

McFarlan, A .

JOURNAL OF POWER SOURCES, 2005, 140 (02) :264-267

← 1 2 →