Synthesis, structure and properties of a three-dimensional porous rare-earth carboxylate MIL-83(Eu):: Eu2(O2C-C10H14-CO2)3

被引：109

作者：

Millange, F

Serre, C

Marrot, J

Gardant, N

Pellé, F

Férey, G

机构：

[1] Univ Versailles, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

[2] CNRS, UMR 7574, Lab Mat Inorgan, F-92195 Meudon, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2004年 / 14卷 / 04期

关键词：

D O I：

10.1039/b314343k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new three-dimensional rare-earth(III) dicarboxylate, MIL-83(Eu) or Eu-2(O2C-C10H14-CO2)(3), has been obtained under hydrothermal conditions from aqueous mixtures of europium nitrate and 1,3-adamantanedicarboxylic acid. Its three-dimensional structure consists of chains built up from face-sharing nine-coordinated rare-earth(III) polyhedra connected by the 1,3-adamantanedicarboxylate linkers, delimiting anhydrous porous channels. This structure is understood by comparison with the already known hybrid rare-earth(III)carboxylates. The thermal behavior of the solid has been investigated using TGA and X-ray thermodiffractometry and shows that the title solid is stable up to 300 degreesC. Finally, the study of the luminescence properties of the yttrium(iii) form of MIL-83(Y/Eu) doped with europium(III) reveals a significant red-emission upon VUV radiation.

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页码：642 / 645

页数：4

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