Development of novel Lewis acid catalysts for selective organic reactions in aqueous media

被引：799

作者：

Kobayashi, S ^{[1
]}

Manabe, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2002年 / 35卷 / 04期

关键词：

D O I：

10.1021/ar000145a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New types of Lewis acids as water-compatible catalysts have been developed. Various metal salts were found to work as Lewis acid catalysts in aqueous media, and catalytic asymmetric aldol reactions in such media have been attained. Furthermore, Lewis acid-surfactant combined catalysts, which can be used for reactions in water without using any organic cosolvents, have been also developed. These investigations will contribute to reducing the use of harmful organic solvents and to develop efficient catalytic systems which cannot be realized in conventional organic solvents.

引用

页码：209 / 217

页数：9

共 66 条

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