Kinetic resolution of racemic tricarbonyl(2-chloroanisole)chromium via palladium-catalysed asymmetric alkoxycarbonylation

被引：12

作者：

Carpentier, JF

Pamart, L

Maciewjeski, L

Castanet, Y

Brocard, J

Mortreux, A

机构：

[1] Lab. Catalys. Heterogene et Homogene, Associé au CNRS, Ecl. Natl. Sup. de Chimie de Lille, 59652 Villeneuve d'Ascq

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 02期

关键词：

D O I：

10.1016/0040-4039(95)02117-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tricarbonyl(o-chloroanisole)chromium was treated with an alcohol and carbon monoxide in the presence of triethylamine and a chiral palladium catalyst to give (o-methoxybenzoate ester)Cr(CO)(3) complexes in high selectivity with up to 30% ee. Starling tricarbonyl(o-chloroanisole)chromium was recovered in up to 39% ee. The Pd/PPFA catalytic system exhibited high reactivity and selectivity for the carbonylation reaction.

引用

页码：167 / 170

页数：4

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